Plone requires that a content-type must be non-folderish in order to be used as default page for a folder.
In Plone 5: content-types created TTW are by default folderish (and there is no way to change this behavior) and can not be added for that reason as a default page for a folder (which I consider a bug).
The same is true for folderish content-types created through Python code...in my case I have a folderish page type and I want it to be used as a folder's default page -> not possible.