Do some search by don't find idea...
your best bet is to create a custom viewlet: https://docs.plone.org/develop/plone/views/viewlets.html and register it for the interface IPloneSiteRoot
if you're using diazo you can create a rule that inserts the <link>
element in <head>
only for the frontpage (condition: body class something with PloneSite
)
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Or you register your own CSS with the Plone resource registry.
the way the question was asked lead me to think of <link rel="alternate" .../>
etc. rather than css. also it was asked to add the link only for the frontpage